It's a basic technique learned early, maybe even before kindergarten: Pulling things apart - from toy cars to complicated electronic materials - can reveal a lot about how they work. "That's one way physicists study the things that they love; they do it by destroying them," said Séamus Davis, a physicist at the U.S. Department of Energy's (DOE) Brookhaven National Laboratory and the J.G. White Distinguished Professor of Physical Sciences at Cornell University.
Davis and colleagues recently turned this destructive approach - and a sophisticated tool for "seeing" the effects - on a material they've been studying for its own intrinsic beauty, and for the clues it may offer about superconductivity, the ability of some materials to carry electric current with no resistance. The findings, published in the Proceedings of the National Academy of Sciences the week of October 17, 2011, reveal how substituting just a few atoms can cause widespread disruption of the delicate interactions that give the material its unique properties, including superconductivity.
The material, a compound of uranium, ruthenium, and silicon, is known as a "heavy-fermion" system. "It's a system where the electrons zooming through the material stop periodically to interact with electrons localized on the uranium atoms that make up the lattice, or framework of the crystal," Davis said. These stop-and-go magnetic interactions slow down the electrons, making them appear as if they've taken on extra mass, but also contribute to the material's superconductivity.
In 2010*, Davis and a group of collaborators visualized these heavy fermions for the first time using a technique developed by Davis, known as spectroscopic imaging scanning tunneling microscopy (SI-STM), which measures the wavelength of electrons of the material in relation to their energy.
The idea of the present study was to "destroy" the heavy fermion system by substituting thorium for some of the uranium atoms. Thorium, unlike uranium, is non-magnetic, so in theory, the electrons should be able to move freely around the thorium atoms, instead of stopping for the brief magnetic encounters they have at each uranium atom. These areas where the electrons should flow freely are known as "Kondo holes," named for the physicist who first described the scattering of conductive electrons due to magnetic impurities.
Free-flowing electrons might sound like a good thing if you want a material that can carry current with no resistance. But Kondo holes turn out to be quite destructive to superconductivity. By visualizing the behavior of electrons around Kondo holes for the first time, Davis' current research helps to explain why.
"There have been beautiful theories that predict the effects of Kondo holes, but no one knew how to look at the behavior of the electrons, until now," Davis said.
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