A team of researchers from Berkeley Lab and Columbia University has passed a major milestone in molecular electronics with the creation of the world's highest-performance single-molecule diode. Working at Berkeley Lab's Molecular Foundry, a U.S. Department of Energy (DOE) Office of Science User Facility, the team used a combination of gold electrodes and an ionic solution to create a single-molecule diode that outperforms the best of its predecessors by a factor of 50.
"Using a single symmetric molecule, an ionic solution and two gold electrodes of dramatically different exposed surface areas, we were able to create a diode that resulted in a rectification ratio, the ratio of forward to reverse current at fixed voltage, in excess of 200, which is a record for single-molecule devices," says Jeff Neaton, Director of the Molecular Foundry, a senior faculty scientist with Berkeley Lab's Materials Sciences Division and the Department of Physics at the University of California Berkeley, and a member of the Kavli Energy Nanoscience Institute at Berkeley (Kavli ENSI).
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