Graphene’s valence and conduction bands meet at a point, making the single-layer crystal a semimetal. Researchers have predicted that spin-orbit coupling of carbon’s outer electrons opens a narrow gap between these bands—but only for the crystal’s bulk. Along the edges, spin-dependent states bridge the band gap, allowing the resistance-free flow of electrons: a quantum spin Hall effect. The weakness of carbon’s spin-orbit coupling means that this quantum spin Hall effect is too fragile to observe, however. Now Pantelis Bampoulis of the University of Twente in the Netherlands and his collaborators have seen the quantum spin Hall effect in graphene’s germanium (Ge) analog, germanene [1]. Furthermore, they show that germanene’s structure—a honeycomb like graphene’s, but lightly buckled—allows the quantum spin Hall effect to be turned off and on using an electric field.

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