In a remarkable feat of chemistry, a Northwestern University-led research team has developed the first two-dimensional (2D) mechanically interlocked material.

Resembling the interlocking links in chainmail, the nanoscale material exhibits exceptional flexibility and strength. With further work, it holds promise for use in high-performance, light-weight body armor and other uses that demand lightweight, flexible and tough materials.

Publishing on Jan. 17 in the journal Science, the study marks several firsts for the field. Not only is it the first 2D mechanically interlocked , but the novel material also contains 100 trillion mechanical bonds per 1 square centimeter—the highest density of mechanical bonds ever achieved.

The researchers produced this material using a new, highly efficient and scalable polymerization process.

"We made a completely new polymer structure," said Northwestern's William Dichtel, the study's corresponding author.

"It's similar to chainmail in that it cannot easily rip because each of the mechanical bonds has a bit of freedom to slide around. If you pull it, it can dissipate the applied force in multiple directions. And if you want to rip it apart, you would have to break it in many, many different places. We are continuing to explore its properties and will probably be studying it for years."

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