Lawrence Livermore National Laboratory (LLNL) scientists have created vertically aligned single-walled carbon nanotubes on metal foils that could be a boon for energy storage and the electronics industry.
Vertically aligned carbon nanotubes (VACNTs) have exceptional mechanical, electrical and transport properties in addition to an aligned architecture, which is key for applications such as membrane separation, thermal management, fiber spinning, electronic interconnects and energy storage.
To date, widespread integration of VACNTs into next-generation technologies is thwarted by a lack of compatible, economic, mass-production capabilities. High-quality VACNTs are typically made on substrates such as silicon (Si) or quartz wafers that are rigid, expensive and electrically insulating.
After exploring metal foil options in scientific literature, the LLNL team turned to Inconel metal substrates allowing them to integrate VACNTs into flexible devices, eliminate a transfer step from Si to other substrates and minimize electrical or thermal transport resistances at the interface between CNTs and the substrate, which is critical for electronic and energy storage applications. Inconel is a family of nickel-chromium-based superalloys that are oxidation-corrosion-resistant materials well-suited for service in extreme environments subjected to pressure and heat.
"Transitioning growth of high-quality CNTs from traditional Si substrates to metal foils opens the door to more economical, large-scale, semicontinuous and roll-to-roll manufacturing of multifunctional CNT composites, nanoporous membranes and electrochemical devices," said LLNL scientist Francesco Fornasiero, co-author of a paper appearing in the journal ACS Applied Materials & Interfaces.
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